EKO-TECH TAPES

Surface Energy Classification

Surface energy (typically expressed in dyn/cm or mN/m) describes how readily an adhesive wets a substrate. For practical selection, materials fall into three classes:

  • High surface energy – good wet-out; bonding is generally straightforward.
  • Medium surface energy – moderate wet-out; adhesive selection is important.
  • Low surface energy – poor wet-out; often requires surface activation or LSE adhesives.

High Surface Energy

On high surface energy materials, surface molecules attract each other strongly and readily attract liquid molecules. The result is easy wet-out and generally straightforward bonding. Typical values are in the hundreds to thousands of dyn/cm (mN/m). Common examples include metals (steel, aluminum, copper), glass, and ceramics.
What it means in practice

  • Wetting: excellent (often low contact angle, <~30°).

  • Surface prep: usually degreasing/cleaning is enough; watch out for oxides, corrosion inhibitors, and oils that reduce effective surface energy.

  • Adhesive choice: acrylic PSAs/tapes, epoxies, cyanoacrylates work very well; for high temperature/chemicals consider silicones or structural acrylics.

  • Process tip: Roughening can aid mechanical anchoring but cannot replace a clean, high-energy surface.

Medium Surface Energy

This is the “middle zone” between easy and difficult wet-out. Typical values are around 36–300 dyn/cm (mN/m), with many engineering substrates clustering near 36–60 dyn/cm. Common examples: ABS, PC, rigid PVC, PET, PMMA, laminates, plus natural materials like wood, stone, concrete (high variability).
In practice

  • Wetting: moderate (contact angle often ~30–60°).

  • Surface prep: degrease, light abrade/scuff; consider corona/plasma/flame treatment near the lower end. For porous substrates: dust removal, drying, primer/sealer.

  • Adhesive choice: acrylic PSAs (≥~38 dyn/cm), acrylic foam tapes (VHB/ACX), epoxies, polyurethanes. For PVC, account for plasticizer migration (resistant adhesives + primer).

  • Process tips: control moisture (wood/concrete), prevent adhesive soak-in (seal), pressure and dwell matter more than on HSE.

Low Surface Energy

On low-surface-energy (LSE) substrates, surface molecules are “content,” showing little attraction to liquids—wet-out is poor and contact angles are high (often >90°). LSE is typically < 36 dyn/cm (mN/m), commonly ~18–34 dyn/cm. Examples include polyolefins (PP, PE/HDPE/LDPE), many TPE/POE, silicone rubbers, and fluoropolymers (PTFE, FEP, ETFE)—among the hardest to bond.
In practice

  • Wetting: poor; cleaning alone rarely suffices. Watch for mold-release agents and slip additives (blooming) that further reduce energy.

  • Surface prep: corona, plasma, or flame treatment raises energy; chemical etch for PTFE is specialized and controlled. Mechanical abrasion may smear and hurt results.

  • Primers: polyolefin primers can dramatically boost adhesion—match primer to the adhesive.

  • Adhesive selection:

    • LSE-optimized acrylics (incl. LSE acrylic foam tapes) for durable bonds.
    • Rubber-resin PSAs give high initial tack but lower heat/UV/chemical resistance.
    • Silicone adhesives mainly for silicone substrates.
  • Design & process: increase bond area, use thicker/foam carriers for conformity, design joints for shear (minimize peel/cleavage), apply firm pressure and allow dwell; warm application improves wet-out.

  • QA: quick dyne-pen checks (indicative), contact-angle measurements, and peel/shear tests on representative coupons

Surface energy of various materials

Eko-Tech Converting Company - Surface energy of various materials

Plastics

Plastics and Surface Energy
Plastics span a wide range of surface energies, which dictates wet-out and bondability. Polyolefins and fluoropolymers (< ~36 dyn/cm, LSE) are difficult to bond and often need activation (corona/plasma/flame), primers, or LSE-optimized adhesives. Engineering plastics such as ABS, PC, PET, PA, PMMA (typically ~36–60 dyn/cm) offer moderate wetting—cleaning and light scuffing can help. The chart below summarizes typical ranges to guide adhesive selection.

Eko-Tech Converting Company - Surface energy plastics

Low-Surface-Energy (LSE) Plastics

LSE plastics typically have lower density and softening/melting ranges, and their non-polar surfaces resist wet-out—liquids and adhesives tend to bead. Bonding is challenging and often requires surface activation (corona/plasma/flame), primers, or LSE-optimized adhesives and tapes (e.g., LSE acrylic foams). The toolbox is smaller than for HSE substrates, but proven options exist, including dedicated 3M or tesa solutions.

Engineering Plastics

Engineering plastics are widely used: lightweight, strong, formable, and cost-effective. They exhibit higher surface energy than LSE plastics (typically ~36–60 dyn/cm), which improves wet-out and makes bonding easier with tapes and liquid adhesives. Examples include ABS, PC, PET, PA, PMMA, rigid PVC; thorough cleaning and occasional light scuffing usually suffice.

Traditional Materials

A broad class with surface energies typically higher than most plastics and lower than metals (often around 100–400 dyn/cm). It includes glass, ceramics, concrete and natural materials such as wood, leather, textiles. They generally wet out and bond readily with tapes or liquid adhesives, but account for specifics: porosity and moisture (wood/concrete) call for dust removal, drying, and often a primer/sealer, while glass/ceramics usually need thorough degreasing.

Eko-Tech Converting Company - Surface energy Traditional Materials
Eko-Tech Converting Company - Metals

Metals

Metals are robust and perform across wide temperature and environmental ranges. Their very high surface energy enables easy wet-out, so they’re generally easy to bond. Suitable options include acrylic PSAs/tapes, acrylic foam tapes, epoxies, cyanoacrylates, and structural acrylics. Always clean/degrease and remove oxides/coatings—oils and corrosion inhibitors reduce adhesion.

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